American Mineralogist

Volume 93, Issue no. 07 : July 2008

Letter

1179 Heat capacity and entropy of melanophlogite: Molecule-containing porosils in nature
Charles A. Geiger, Edgar Dachs, and Mariko Nagashima

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1183 Crystal structure of glaucodot, (Co,Fe)AsS, and its relationships to marcasite and arsenopyrite
Hexiong Yang and Robert T. Downs

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1187 Modification of gas speciation in quartz-hosted fluid inclusions by stray laser radiation during LA-ICPMS analysis
Glenn Lambrecht, Larryn W. Diamond, and Thomas Pettke

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1191 A PH2O-dependent structural phase transition in the zeolite natrolite
Hsiu-Wen Wang and David L. Bish

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MSA Presidential Address

1   MSA at 100 and why optical mineralogy still matters: The optical properties of talc
Mickey E. Gunter
REGULAR ARTICLES

965 Rietveld structure refinement of MgGeO3 post-perovskite phase to 1 Mbar
Atsushi Kubo, Boris Kiefer, Sang-Heon Shim, Guoyin Shen, Vitali B. Prakapenka, and Thomas S. Duffy

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977 High-temperature ammonium white mica from the Betic Cordillera (Spain)
Mar??a Dolores Ruiz Cruz and Carlos Sanz de Galdeano

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988 Synthesis and crystal structure of the feldspathoid CsAlSiO4: An open-framework silicate and potential nuclear waste disposal phase
G. Diego Gatta, N. Rotiroti, P.F. Zanazzi, M. Rieder, M. Drabek, Z. Weiss, and R. Klaska

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996 The crystal chemistry of Li in gadolinite
Fernando Cámara, Roberta Oberti, Luisa Ottolini, Giancarlo Della Ventura, and Fabio Bellatreccia

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1005 The effect of the hedenbergitic substitution on the compressibility of jadeite
F. Nestola, T. Boffa Ballaran, C. Liebske, R. Thompson, and R.T. Downs

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1014 The structure of monohydrocalcite and the phase composition of the beachrock deposits of Lake Butler and Lake Fellmongery, South Australia
Ian P. Swainson

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1019 First-principles calculation of the infrared spectrum of hematite
Marc Blanchard, Michele Lazzeri, Francesco Mauri, and Etienne Balan

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1028 In situ observations of muscovite dissolution under alkaline conditions at 25–50 °C by AFM with an air/fluid heater system
Yoshihiro Kuwahara

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1034 Ramanite-(Cs) and ramanite-(Rb): New cesium and rubidium pentaborate tetrahydrate minerals identified with Raman spectroscopy
Rainer Thomas, Paul Davidson, and Andreas Hahn

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1043 Pressure-temperature studies of talc plus water using X-ray diffraction
A.E. Gleason, S.A. Parry, A.R. Pawley, R. Jeanloz, and S.M. Clark

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1051 Hematite and magnetite precipitates in olivine from the Sulu peridotite: A result of dehydrogenation-oxidation reaction of mantle olivine?
Shyh-Lung Hwang, Tzen-Fu Yui, Hao-Tsu Chu, Pouyan Shen, Yoshiyuki Iizuka, Houng-Yi Yang, Jingsui Yang, and Zhiqin Xu

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1061 Arsenide in a metasomatized peridotite xenolith as a constraint on arsenic behavior in the mantle wedge
Satoko Ishimaru and Shoji Arai

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1066 Multiple oxygen sites in synthetic phyllosilicates with expandable layers: 17O solid-state NMR study
Sung Keun Lee and Charles A. Weiss Jr.

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1072 On the existence of a Na-deficient monoclinic trinepheline with composition Na7.85Al7.85Si8.15O32
Predrag Vulić, Volker Kahlenberg, and Jürgen Konzett

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1080 Chlorite and biotite weathering, Fe2+-rich corrensite formation, and Fe behavior under low PO2 conditions and their implication for Precambrian weathering
Hirokazu Sugimori, Teruki Iwatsuki, and Takashi Murakami

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1090 Structural characterization of natural UO2 at pressures up to 82 GPa and temperatures up to 2200 K
Steeve Gréaux, Laurent Gautron, Denis Andrault, Nathalie Bolfan-Casanova, Nicolas Guignot, and Julien Haines

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1099 Dense hydrous magnesium silicates, phase D, and superhydrous B: New structural constraints from one- and two-dimensional 29Si and 1H NMR
Xianyu Xue, Masami Kanzaki, and Anton Shatskiy

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1112 Mid-IR bands of synthetic calcic amphiboles of tremolite-pargasite series and of natural calcic amphiboles
Kiyotaka Ishida, David M. Jenkins, and Frank C. Hawthorne

Abstract     Members Full Text Download     

1119 Probing the site occupancies of Co-, Ni-, and Mn-substituted biogenic magnetite using XAS and XMCD
Victoria S. Coker, Carolyn I. Pearce, Richard A.D. Pattrick, Gerrit van der Laan, Neil D. Telling, John M. Charnock, Elke Arenholz, and Jonathan R. Lloyd

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1133 Origin of titanite in metarodingite from the Zagros Thrust Zone, Iraq
Yousif Osman Mohammad and Hirokazu Maekawa

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1142 Experimental calibration of aluminum partitioning between olivine and spinel as a geothermometer
Zhihuan Wan, Laurence A. Coogan, and Dante Canil

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1148 Single-crystal X-ray diffraction study of CaIrO3
Masahiko Sugahara, Akira Yoshiasa, Akira Yoneda, Takafumi Hashimoto, Syunsuke Sakai, Maki Okube, Akihiko Nakatsuka, and Osamu Ohtaka

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1153 Orthorhombic polymorph of rengeite from Ohmi region, central Japan
Hiroki Mashima, Junji Akai, Yoshihiro Nakamuta, and Satoshi Matsubara

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1158 New insights into the crystal chemistry of epididymite and eudidymite from Malosa, Malawi: A single-crystal neutron diffraction study
G. Diego Gatta, N. Rotiroti, G.J. McIntyre, A. Guastoni, and F. Nestola

Abstract     Members Full Text Download          Deposit Item

1166 Mechanisms of rhyolitic glass hydration below the glass transition
Lawrence M. Anovitz, David R. Cole, and Mostafa Fayek

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Supplements

Welcome to MSA/American Mineralogist Supplemental Materials. These are free to all readers. Discover extra tables, supplemental data, CIFs, appendices, extra figures, and in the future “methods sections”. To find previous issues, go to that Table of Contents and click on the link. We ask that all materials be cited so that credit is given to the authors and American Mineralogist. The pure datasets are not copyrightable. All other material is copyrighted by the authors.

American Mineralogist      Vol. 107, no. 1   January 2022

15    Boron isotope compositions establish the origin of marble from metamorphic complexes: Québec, New York, and Sri Lanka
Corinne Kuebler, Antonio Simonetti, Stefanie S. Simonetti, and Robert F. Martin

Item #AM-22-17811
Online Material
AM-22-17811.zip zipped


31    Celleriite, (Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new mineral species of the tourmaline supergroup
Ferdinando Bosi, Federico Pezzotta, Alessandra Altieri, Giovanni B. Andreozzi, Paolo Ballirano, Gioacchino Tempesta, Jan Cempírek, Radek Škoda, Jan Filip, Renata Čopjaková, Milan Novák, Anthony R. Kampf, Emily D. Scribner, Lee A. Groat, and R. James Evans
Item #AM-22-17818
CIF and Online Material
AM-22-17818.zip zipped


54    Incorporation of incompatible trace elements into molybdenite: Layered PbS precipitates within molybdenite
Yiping Yang, Hongping He, Wei Tan, Qi Tao, Junming Yao, Haiyang Xian, Shangying Li, Jiaxin Xi, Jianxi Zhu, and Huifang Xu
Item #AM-22-17609
Online Material
AM-22-17609.zip zipped


74    Thermoelastic properties of zircon: Implications for geothermobarometry
Alix M. Ehlers, Gabriele Zaffiro, Ross J. Angel, Tiziana Boffa-Ballaran, Michael A. Carpenter, Matteo Alvaro, and Nancy L. Ross

Item #AM-22-17731
Online Material
AM-22-17731.zip zipped


82    A Rayleigh model of cesium fractionation in granite-pegmatite systems
David London
Item #AM-22-17855
Online Material
AM-22-17855.zip zipped


92    The atomic arrangement and electronic interactions in vonsenite at 295, 100, and 90 K
Marc Maderazzo, John M. Hughes, M. Darby Dyar, George R. Rossman, Brandon J. Ackley, Elizabeth C. Sklute, Marian V. Lupulescu, and Jeffrey Chiarenzelli
Item #AM-22-17851
CIF and Online Material
AM-22-17851.zip zipped


100    Oxalate formation by Aspergillus niger on minerals of manganese ores
Olga Frank-Kamenetskaya, Marina Zelenskaya, Alina Izatulina, Vladislav Gurzhiy, Aleksei Rusakov, and Dmitry Vlasov
Item #AM-22-17651
CIF and Online Material
AM-22-17651.zip zipped


116    Mesoproterozoic seafloor authigenic glauconite-berthierine: Indicator of enhanced reverse weathering on early Earth
Jianbai Ma, Xiaoying Shi, Maxwell Lechte, Xiqiang Zhou, Zhenfei Wang, Kangjun Huang, Maxim Rudmin, and Dongjie Tang
Item #AM-22-17904
Online Material
AM-22-17904.zip zipped


131    Chemical variability in vyacheslavite, U(PO4)(OH): Crystal-chemical implications for hydrous and hydroxylated U4+, Ca, and REE phosphates
Gwladys Steciuk, Radek Škoda, Veronika Dillingerová, and Jakub Plášil
Item #AM-22-17875
CIF and Online Material
AM-22-17875.zip zipped


138    Bennesherite, Ba2Fe2+Si2O7: A new melilite group mineral from the Hatrurim Basin, Negev Desert, Israel
Arkadiusz Krzątała, Biljana Krüger, Irina Galuskina, Yevgeny Vapnik, and Evgeny Galuskin
Item #AM-22-17747
CIF and Online Material
AM-22-17747.zip zipped


147    Single-crystal elasticity of phase Egg AlSiO3OH and δ-AlOOH by Brillouin spectroscopy
Baoyun Wang, Yanyao Zhang, Suyu Fu, Wei Yan, Eiichi Takahashi, Li Li, Jung-Fu Lin, and Maoshuang Song

Item #AM-22-18056
CIF and Online Material
AM-22-18056.zip zipped

LETTER

1179

Heat capacity and entropy of melanophlogite: Molecule-containing porosils in nature
Charles A. Geiger, Edgar Dachs, and Mariko Nagashima

Abstract     Members Full Text Download          Deposit Item

1183

Crystal structure of glaucodot, (Co,Fe)AsS, and its relationships to marcasite and arsenopyrite
Hexiong Yang and Robert T. Downs

Abstract     Members Full Text Download     

1187

Modification of gas speciation in quartz-hosted fluid inclusions by stray laser radiation during LA-ICPMS analysis
Glenn Lambrecht, Larryn W. Diamond, and Thomas Pettke

Abstract     Members Full Text Download     

1191

A PH2O-dependent structural phase transition in the zeolite natrolite
Hsiu-Wen Wang and David L. Bish

Abstract     Members Full Text Download          Deposit Item

REGULAR ARTICLE

965

Rietveld structure refinement of MgGeO3 post-perovskite phase to 1 Mbar
Atsushi Kubo, Boris Kiefer, Sang-Heon Shim, Guoyin Shen, Vitali B. Prakapenka, and Thomas S. Duffy

Abstract     Members Full Text Download          Deposit Item

977

High-temperature ammonium white mica from the Betic Cordillera (Spain)
Mar??a Dolores Ruiz Cruz and Carlos Sanz de Galdeano

Abstract     Members Full Text Download     

988

Synthesis and crystal structure of the feldspathoid CsAlSiO4: An open-framework silicate and potential nuclear waste disposal phase
G. Diego Gatta, N. Rotiroti, P.F. Zanazzi, M. Rieder, M. Drabek, Z. Weiss, and R. Klaska

Abstract     Members Full Text Download          Deposit Item

996

The crystal chemistry of Li in gadolinite
Fernando Cámara, Roberta Oberti, Luisa Ottolini, Giancarlo Della Ventura, and Fabio Bellatreccia

Abstract     Members Full Text Download          Deposit Item

1005

The effect of the hedenbergitic substitution on the compressibility of jadeite
F. Nestola, T. Boffa Ballaran, C. Liebske, R. Thompson, and R.T. Downs

Abstract     Members Full Text Download     

1014

The structure of monohydrocalcite and the phase composition of the beachrock deposits of Lake Butler and Lake Fellmongery, South Australia
Ian P. Swainson

Abstract     Members Full Text Download          Deposit Item

1019

First-principles calculation of the infrared spectrum of hematite
Marc Blanchard, Michele Lazzeri, Francesco Mauri, and Etienne Balan

Abstract     Members Full Text Download     

1028

In situ observations of muscovite dissolution under alkaline conditions at 25–50 °C by AFM with an air/fluid heater system
Yoshihiro Kuwahara

Abstract     Members Full Text Download     

1034

Ramanite-(Cs) and ramanite-(Rb): New cesium and rubidium pentaborate tetrahydrate minerals identified with Raman spectroscopy
Rainer Thomas, Paul Davidson, and Andreas Hahn

Abstract     Members Full Text Download     

1043

Pressure-temperature studies of talc plus water using X-ray diffraction
A.E. Gleason, S.A. Parry, A.R. Pawley, R. Jeanloz, and S.M. Clark

Abstract     Members Full Text Download          Deposit Item

1051

Hematite and magnetite precipitates in olivine from the Sulu peridotite: A result of dehydrogenation-oxidation reaction of mantle olivine?
Shyh-Lung Hwang, Tzen-Fu Yui, Hao-Tsu Chu, Pouyan Shen, Yoshiyuki Iizuka, Houng-Yi Yang, Jingsui Yang, and Zhiqin Xu

Abstract     Members Full Text Download     

1061

Arsenide in a metasomatized peridotite xenolith as a constraint on arsenic behavior in the mantle wedge
Satoko Ishimaru and Shoji Arai

Abstract     Members Full Text Download     

1066

Multiple oxygen sites in synthetic phyllosilicates with expandable layers: 17O solid-state NMR study
Sung Keun Lee and Charles A. Weiss Jr.

Abstract     Members Full Text Download     

1072

On the existence of a Na-deficient monoclinic trinepheline with composition Na7.85Al7.85Si8.15O32
Predrag Vulić, Volker Kahlenberg, and Jürgen Konzett

Abstract     Members Full Text Download     

1080

Chlorite and biotite weathering, Fe2+-rich corrensite formation, and Fe behavior under low PO2 conditions and their implication for Precambrian weathering
Hirokazu Sugimori, Teruki Iwatsuki, and Takashi Murakami

Abstract     Members Full Text Download     

1090

Structural characterization of natural UO2 at pressures up to 82 GPa and temperatures up to 2200 K
Steeve Gréaux, Laurent Gautron, Denis Andrault, Nathalie Bolfan-Casanova, Nicolas Guignot, and Julien Haines

Abstract     Members Full Text Download          Deposit Item

1099

Dense hydrous magnesium silicates, phase D, and superhydrous B: New structural constraints from one- and two-dimensional 29Si and 1H NMR
Xianyu Xue, Masami Kanzaki, and Anton Shatskiy

Abstract     Members Full Text Download     

1112

Mid-IR bands of synthetic calcic amphiboles of tremolite-pargasite series and of natural calcic amphiboles
Kiyotaka Ishida, David M. Jenkins, and Frank C. Hawthorne

Abstract     Members Full Text Download     

1119

Probing the site occupancies of Co-, Ni-, and Mn-substituted biogenic magnetite using XAS and XMCD
Victoria S. Coker, Carolyn I. Pearce, Richard A.D. Pattrick, Gerrit van der Laan, Neil D. Telling, John M. Charnock, Elke Arenholz, and Jonathan R. Lloyd

Abstract     Members Full Text Download     

1133

Origin of titanite in metarodingite from the Zagros Thrust Zone, Iraq
Yousif Osman Mohammad and Hirokazu Maekawa

Abstract     Members Full Text Download     

1142

Experimental calibration of aluminum partitioning between olivine and spinel as a geothermometer
Zhihuan Wan, Laurence A. Coogan, and Dante Canil

Abstract     Members Full Text Download          Deposit Item

1148

Single-crystal X-ray diffraction study of CaIrO3
Masahiko Sugahara, Akira Yoshiasa, Akira Yoneda, Takafumi Hashimoto, Syunsuke Sakai, Maki Okube, Akihiko Nakatsuka, and Osamu Ohtaka

Abstract     Members Full Text Download     

1153

Orthorhombic polymorph of rengeite from Ohmi region, central Japan
Hiroki Mashima, Junji Akai, Yoshihiro Nakamuta, and Satoshi Matsubara

Abstract     Members Full Text Download     

1158

New insights into the crystal chemistry of epididymite and eudidymite from Malosa, Malawi: A single-crystal neutron diffraction study
G. Diego Gatta, N. Rotiroti, G.J. McIntyre, A. Guastoni, and F. Nestola

Abstract     Members Full Text Download          Deposit Item

1166

Mechanisms of rhyolitic glass hydration below the glass transition
Lawrence M. Anovitz, David R. Cole, and Mostafa Fayek

Abstract     Members Full Text Download     

BOOK REVIEW

1195

BOOK REVIEW: MÖSSBAUER SPECTROSCOPY OF ENVIRONMENTAL MATERIALS AND THEIR INDUSTRIAL UTILIZATION, by Enver Murad and John Cashion. (2004) Kluwer Academic Publishers, Norwell, Massachusetts 417 p. ISBN: 1 4020 7726 2.
M. Darby Dyar

Full Text     

1196

BOOK REVIEW: INTRODUCTION TO RADIOACTIVE MINERALS by Robert LAUF, Ph.D. Schiffer Publishing Ltd., Atglen, Pennsylvania. (2008) Paperback with 193 pictures.
Winfried Koensler

Full Text     

ERRATUM

1197

ERRATA: Eskolaite associated with diamond from the Udachnaya kimberlite pipe, Yakutia, Russia by A.M. Logvinova, R. Wirth, N.V. Sobolev, Y.V. Seryotkin, E.S. Yefimova, C. Floss, and L.A. Taylor (vol. 93, p. 685–690, 2008: Erratum DOI 10.2138/am.2008.523).

Full Text     

1198

ERRATA: Possible structural polymorphism in Al-bearing magnesiumsilicate post-perovskite by O. Tschauner, B. Kiefer, H. Liu, S. Sinogeikin, M. Somayazulu, S.N. Luo (vol. 93, p. 533–539, 2008: Erratum DOI 10.2138/am.2008.522).

Full Text     

DEPOSIT ITEMS

965

Rietveld structure refinement of MgGeO3 post-perovskite phase to 1 Mbar
Atsushi Kubo, Boris Kiefer, Sang-Heon Shim, Guoyin Shen, Vitali B. Prakapenka, and Thomas S. Duffy

Item#: AM-08-032
Table S1. Spherical harmonic coefficients for the pPv phase obtained from Rietveld refinements., Fig. S1 Rietveld refinement results., Fig. S2a Crystal structure of CaIrO3-type ABX3 post-perovskite phase and Fig. S2b X-X pair distances in the ABX3 pPv phase.
AM-08-032.zip zipped

988

Synthesis and crystal structure of the feldspathoid CsAlSiO4: An open-framework silicate and potential nuclear waste disposal phase
G. Diego Gatta, N. Rotiroti, P.F. Zanazzi, M. Rieder, M. Drabek, Z. Weiss, and R. Klaska

Item#: AM-08-030
Table 4A. Observed and calculated structure factors (Fo-Fc) CsAlSiO4, Table 4B Observed and calculated structure factors (Fo-Fc) RbAlSiO4, Crystallographic Information Framework file for CsAlSiO4 and Crystallographic Information Framework file for RbAlSiO4
AM-08-030.zip zipped

996

The crystal chemistry of Li in gadolinite
Fernando Cámara, Roberta Oberti, Luisa Ottolini, Giancarlo Della Ventura, and Fabio Bellatreccia

Item#: AM-08-034
Table 4. Observed and calculated structure factors for gadolinite-(Y) from Vico and Crystallographic Information Framework file for gadolinite-(Y)
AM-08-034.zip zipped

1014

The structure of monohydrocalcite and the phase composition of the beachrock deposits of Lake Butler and Lake Fellmongery, South Australia
Ian P. Swainson

Item#: AM-08-029
Crystallographic Information Framework file for monohydrocalcite
AM-08-029.zip zipped

1043

Pressure-temperature studies of talc plus water using X-ray diffraction
A.E. Gleason, S.A. Parry, A.R. Pawley, R. Jeanloz, and S.M. Clark

Item#: AM-08-033
Tables 1Ð4. Refined cell parameters of experiments
AM-08-033.zip zipped

1090

Structural characterization of natural UO2 at pressures up to 82 GPa and temperatures up to 2200 K
Steeve Gréaux, Laurent Gautron, Denis Andrault, Nathalie Bolfan-Casanova, Nicolas Guignot, and Julien Haines

Item#: AM-08-031
Crystallographic Information Framework file for UO2, Pbca structure and Crystallographic Information Framework file for UO2, Fluorite structure
AM-08-031.zip zipped

1142

Experimental calibration of aluminum partitioning between olivine and spinel as a geothermometer
Zhihuan Wan, Laurence A. Coogan, and Dante Canil

Item#: AM-08-035
Table 1. Compositions of experimental run products
AM-08-035.zip zipped

1158

New insights into the crystal chemistry of epididymite and eudidymite from Malosa, Malawi: A single-crystal neutron diffraction study
G. Diego Gatta, N. Rotiroti, G.J. McIntyre, A. Guastoni, and F. Nestola

Item#: AM-08-037
Table 5 Observed and calculated structure factors of epididymite and eudidymite.
AM-08-037.zip zipped

1179

Heat capacity and entropy of melanophlogite: Molecule-containing porosils in nature
Charles A. Geiger, Edgar Dachs, and Mariko Nagashima

Item#: AM-08-036
Figure 1. Polyhedral drawing of the melano-phlogite structure., Table 1a. Raw Cp data for the Mt. Hamilton and Racalmuto melanophlogites and their heat-treated analogues., Table 1b. Molar thermodynamic functions of melanophlogite, Table 1c & 1d. Molar thermodynamic functions of melanophlogite and Table 2. Thermodynamic properties for various SiO2 phases
AM-08-036.zip zipped

1191

A PH2O-dependent structural phase transition in the zeolite natrolite
Hsiu-Wen Wang and David L. Bish

Item#: AM-08-041
Information on materials and methods.
AM-08-041.zip zipped
TABLE OF CONTENTS
&
SPECIAL COLLECTIONS

Table of Contents

AmMin submission to acceptance/”first publication” is at a record average of about three to four months. Our acceptance to “final” publication is presently another 13 months on average.

Special Collections

American Mineralogist is an international journal that publishes mineralogical papers of broad interest to the geoscience and materials science community.