The
Mohs' hardness scale was developed in 1822 by Frederich Mohs. This
scale is a chart of relative hardness of the various minerals (1 - softest to
10 - hardest). Since hardness depends upon the crystallographic direction
(ultimately on the strength of the bonds between atoms in a crystal), there
can be variations in hardness depending upon the direction in which one measures
this property. One of the most
striking examples of this is kyanite, which has a hardness of 5.5 parallel to
the [001] direction ( c-axis), while it has a hardness of 7.0 parallel to the
[100] direction ( a-axis). Talc (1), the softest mineral on the Mohs scale has a
hardness greater than gypsum (2) in the direction that is perpendicular to the
cleavage. Diamonds (10) also show a variation in hardness (the octahedral faces
are harder than the cube faces). For further information see articles from the American
Mineralogist on microhardness, the Knoop
tester, and
diamonds.
Mohs' hardness is a measure of the relative hardness and resistance to
scratching between minerals. Other hardness scales rely on the ability to create
an indentation into the tested mineral (such as the Rockwell, Vickers, and
Brinell hardness - these are used mainly to determine hardness in metals
and metal alloys). The scratch hardness is related to the breaking of the
chemical bonds in the material, creation of microfractures on the surface, or
displacing atoms (in metals) of the mineral. Generally, minerals with covalent
bonds are the hardest while minerals with ionic, metallic, or van der Waals
bonding are much softer.
When doing the tests of the minerals it is necessary to
determine which mineral was scratched. The powder can be rubbed or blown off and
surface scratches can usually be felt by running the fingernail over the
surface. One can also get a relative feel for the hardness difference between
two minerals. For instance quartz will be able to scratch calcite with much
greater ease than you can scratch calcite with fluorite. One must also use
enough force to create the scratch (if you don't use enough force even diamond
will not be able to scratch quartz - this is an area where practice is
important). You also have to be careful to test the material that you think you
are testing and not some small inclusion in the sample. This is where using a
small hand lens can be very useful to determine if the test area is homogenous.